This is simply an image of a famous beauty of the Edwardian era, Lillie Langtry, and the story is not in the picture but in her life. She definitely belongs in the Intrepid Women category.
The photo, dated c1882, is described, rather than titled: Lily Langtry, 1852-1929, half length portrait, standing, right profile; in matching turban and dress. The LOC entry is the Americanized spelling of her name; Wikipedia gives her birth year as 1853, but my Chambers's Biographical Dictionary (1926) gives it as 1852.
Photo courtesy Library of Congress Prints and Photographs Division Washington, D.C. 20540 USA.